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Hydrogen peroxide is a weak acid and when mixed with teeth whitening mixtures it becomes a very good bleaching agent and is used used in mouth washes, tooth pastes etc.
In theory it is possible to make your own teeth peroxide mixture at home.
However, it's not advisable to do this, due to the risk of getting it wrong and harming yourself. Being acidic in nature, overdoing it can have adverse effects.
So why take the risk. After all, there are many tried & tested home teeth whitening products available, many of which are available on free trials so you can check their results and if they suit you. (Whitening Ultra being once such product)